Oilseed plants are used for the production of biodiesel through the process called transesterification reaction which is a process by which alcohol reacts with vegetable oil in the presence of. Everywhere in the world, there is an enormous amount of waste lipids generated from restaurants, food processing. Since lipase catalysts are much expensive, the usage of lipase in biodiesel production is. Synthesis and characterization of biodiesel from waste. It is nontoxic, biodegradable and produces less sulfur and hydrocarbons, and can be used in diesel engines with minimal modifications. A twostep catalytic process for the production of biodiesel from waste frying oil wfo at low cost, utilizing waste animalbone as catalyst and solar radiation as heat source is reported in this work. As crude oil price reach a new high, the need for developing alternate fuels has become acute. Waste frying oil with high levels of free fatty acids as one. Oil which has been used for cooking will required more of the reactive agents and methanol than fresh oil. Received 01 july 2011, revised 27 october 2011, accepted 03 november 2011. Different techniques for the production of biodiesel from waste. The purpose of this research is to produce biodiesel from waste cooking oils in the laboratory and compare the quantity and quality of products made from domestic waste cooking oil, restaurant cooking oil and fresh. Kates b a department of chemical engineering, university of ottawa, ottawa, ont. Biodiesel is very potential to replace fossil fuels.
The pro cess was carried out at a alcohol oil molar ratio of 6. The mono alky esters of long fatty acids derived from the renewable lipid feed stock such as vegetable oils or animal fats for use in diesel engines is known as biodiesel. Therefore, when constructional lime is used as catalyst pretreatment of waste oil is not. Introduction the depleting reserves and uncertainty price of world crude oil have motivated the researcher for developing alternative fuel, particularly for transpor tation and industrial fuels. We deduced the amount of biodiesel produced from 1 liter of used cooking oil, which enabled us to calculate the amount of biodiesel that can potentially be created every month using cooking oil. Pdf pretreatment of waste frying oils for biodiesel production. Request pdf on mar 15, 2019, jhessica marchini fonseca and others published biodiesel from waste frying oils. As waste frying oils have been regularly poured down the drain, resulting in problems for wastewater treatment plants and energy loss, or integrated into food chain by animal feeding, causing human health problems, their use for biodiesel production offers solution to a growing problem of the increased waste oil production from household and. Biodiesel and crude glycerol from waste frying oil. The potential economic, heath, and greenhouse gas benefits. Optimization of homogeneous transesterification of waste frying oil wfo to biodiesel over hydroxide potassium koh catalyst have been investigated.
Biodiesel, used vegetable oil, transesterification, alcohol. Production, characterization and evaluation of biodiesel oxidative stability with diesel blends mariem harabi 1, soumaya neji bouguerra 1, fatma marrakchi 1, loukia p. In addition, using waste cooking oil could also help to solve the problem of waste oil disposal supple et al. Waste food oil can be obtained from any restaurant or dining hall that uses vegetable oil for frying food. In this work, biodiesel ethyl ester was prepared from waste cooking oil collected from a local restaurant in halifax, nova scotia, canada. Use a cooking thermometer to monitor the temperature. A comparative study of biodiesel production from waste cooking oil using sulfuric acid twostep and microwaveassisted transesterification onestep was carried out. Currently, all diesel fuel used for land vehicles must have 20% bio. Implications of imported used cooking oil uco as a. This type of biofuel can be obtained from renewable sources such as vegetable, animal or frying oils. Pdf on dec 18, 2015, shoeb ahmed and others published biodiesel production from waste frying oil and its process simulation find, read.
At the same time, recycled frying oils were studied as raw material by mittelbach and remschmidt, who later developed a commercial process for converting waste oils from households and restaurants as well as fatty waste from slaughter houses. A study on production of biodiesel from waste frying oil aidic. In a modern society, oil is commonly used for the preparation of food. Characterization of biodiesel produced from waste cooking. Optimization of homogeneous transesterification of waste frying oil. However, the properties of biodiesel manufactured by using discarded cooking oil are dependent upon the content of free fatty acids, polar compounds and polymerized triglycerides. Biodiesel from waste cooking oils wco or used frying oils ufo has been recently investigated. Transformation of used cooking oil into biodiesel from waste to resource the frying process modifies vegetable oils from both a physical and a chemical point of view resulting in the creation of harmful compounds. Biodiesel production from waste frying oils wfos is one of the most. Agroindustry residues such as slaughterhouse waste, restaurant cooking oil, nonfoodgrade virgin oil or agricultural surplus once destined for a landfill is a commodity in the biodiesel business. Moreover, the removal of these catalysts after the reaction is complete needs the washing of biodiesel with water which might result in loss of fatty acid alkyl esters, energy. Biodiesel production using waste frying oil sciencedirect.
In this study, waste frying oil was used to produce biodiesel by ultrasound. Biodiesel production from rapeseed oil with waste frying oils. Transesterification of waste cooking oil into biodiesel. The dominant biodiesel feedstock for biodiesel consumed in the uk is used cooking oil uco, defined as the purified oils and fats of plant and animal origin that have been used to cook food. The palm oil resists low acidity levels, up to ph 4.
The acid catalyst was added to the preheated waste frying oil at different dosages 0. Preparation of biodiesel from waste frying oil using a. Alkalicatalyzed production of biodiesel from waste frying oils. Catalysts used in this process are usually acids, base, and lipase.
The biodiesel process used at rit was tailored for the residential cooking oil which tends to be high in water content. However, the land use for production of edible oil for biodiesel feedstock competes with the use of land for food production. The use of waste cooking oil instead of virgin oil to produce biodiesel is an effective way to reduce the raw material cost because it is estimated to be about half the price of virgin oil. A solid caobased catalyst of waste eggshell was developed for biodiesel production from used cooking oil. Methods the biodiesel was produced by alkali transesterification of the waste oils with the addition of sodium hydroxide and methanol to form methyl esters. Tend to be high in free fatty acids which results in lower yields of biodiesel due to soap production during the. Biodiesel production from waste frying oil by ultrasound. Biodiesel was produced from waste frying oil using calcium oxide derived from the calcination of egg shell as a heterogeneous base catalyst. In todays world, oil frying method is widely used due to the contribution of good taste, attractive colour and better presentation of the food. The presence of too many free fatty acids will retard or stop the reaction, which produces biodiesel, so it is necessary to deduce the exact amount of alkali sodium hydroxide needed to neutralize the acids. Biodiesel production from waste cooking oil 27 physical characteristics good, texture and struct ure, are preferable to the level of fertility, as it can be corrected with mineral fertilization. Biodiesel is a fuel for diesel engines made from plant or animal oils.
Use of low cost feedstocks such as waste cooking oil wco should help make biodiesel competitive in price with petroleum diesel. The feedstocks used were domestic deep frying canola oil, domestic lard, deep frying oil obtained from a restaurant and fresh canola oil. Applications of waste cooking oil other than biodiesel. The production of biodiesel from waste frying oils. Rendering is the purification process of the used fats, oils, and grease f. In this respect, response surface methodology rsm was applied to determine the relationships between methanol and wfo molar. Waste cooking oil as an alternate feedstock for biodiesel.
Biodiesel production from waste frying oil using waste animal bone and solar heat grisel corroa. Production optimization and quality assessment of biodiesel from. Undergraduate research, waste cooking oil, biodiesel, social awareness, green chemistry introduction. Seid yimer, and omprakash sahu, optimization of biodiesel production from waste cooking oil. Regarding emissions, biodiesel is the only alternative fuel. The transesterification process was implemented to extract the biodiesel, and this process was optimized and standardized by selecting three different parameters. Oil crops, waste cooking oil and animal fat cannot realistically satisfy this demand. Wfo to biodiesel over hydroxide potassium koh catalyst have been. To minimize the biofuel cost, in recent days waste cooking oil was used as feedstock. The first article which reported on successful engine tests for methyl, ethyl, and 1butylesters produced from used frying oil appeared in 1983. The waste oil instead of being used as cooking medium can generate revenue if converted into biodiesel and glycerin. F over an electric burner to make the oil easier to pour for filtration. The potential benefits of incorporating used cooking oil into indonesias biodiesel executive summary indonesia has one of the most ambitious biofuel policies in the world. Pdf the paper explores the effect of the quantity of methanol on biodiesel production and its characteristics from waste frying oil wfo.
Methods of production and purification find, read and cite all the research you. The oil used in biodiesel fuel production can be fresh clean oil or used waste oil that has been earlier used for frying as in this study. Life cycle assessment of biodiesel production from waste cooking oil in western australia abstract biodiesel derived from waste cooking oil wco is considered highly environmental sustainable since wco is a waste product which has been recycled to a transportation fuel in. It is used to dissolve waste cooking oil during determination of extra amount of alkali naoh in titration. These values are 9% lower than regular petrodiesel. The conversion of waste frying oil into a valuable methyl ester biodiesel has been successfully conducted and also the acid pretreatment process was carried out prior to the main biodiesel production process for lowering waste frying oil free fatty acid ffa content below 1%. Pretreatment of waste frying oil by esterification reaction using sulfuric acid in this step, 100ml of waste frying oil was poured into the reactor, and heated at 60c. Pdf the conversion of waste frying oil into a valuable methyl ester biodiesel has been successfully conducted and also the acid pretreatment. Moreover, the price of edible plant and vegetable oils is usually higher than petrodiesel. Biodiesel obtained from discarded frying oil has been found to give better engine performance and lesser carbon emission as compared to other fuels.
Sep 24, 2019 growing interest in sustainable production of goods and energy is pushing the development of new biorefinery model. Thus, biodiesel produced from recycled frying oils has the same possibilities to be. Since the bse crisis european uco is classified as a waste that is no longer fit for human or animal. Ultrasonicassisted production of biodiesel from waste frying. Utilization of constructional lime as heterogeneous catalyst. Using waste cooking oil to produce biodiesel provides a suitable profitable way to eliminate the raw materials of gutter oil. Performance analysis of biodiesel derived from waste.
The potential production of biodiesel from rapeseed oil in chile is associated to the solution of economic, environmental. These includes linseed oil, palm seed oil, waste cooked vegetable oil, sunflower seed oil, cotton seed oil, cooking seed oil and animal fats 7, 8, 9. The used frying oil collected from a popular fastfood restaurant waste vegetable oil wvor included corn, sunflower and canola feedstock. Water impedes the biodiesel reaction resulting in only partial conversion of the oil to biodiesel. Utilization of constructional lime as heterogeneous. You can also make biodiesel from waste cooking oil, but that is a little more involved, so lets start with the basics. Pdf biodiesel production from waste frying oil using waste. Transesterification reactions were carried out between 70. Repeated frying for preparation of food makes the edible vegetable oil no longer suitable for consumption due to high free fatty acid ffa content. Pour your used oil into a large, clean cooking pot and heat it to 95. Thus, biodiesel can be produced from waste frying oil using an enzyme as a catalyst and by using various parameters that were optimized in this study. The initial reaction rate of refined oil was slower than that of waste frying oil, although the final conversion of refined oil 61. Pdf production of biodiesel from waste cooking oil.
Biodiesel from waste cooking oil is one such alternative. This work investigated the potential of producing biodiesel from waste cooking oil wco collected from eateries and fast food restaurants in awka, anambra nigeria. Biodiesel and crude glycerol from waste frying oil mdpi. Also waste oils and fats used cooking oils are used as a good feedstock, its costs approaches half of the cost of virgin oil 4. Waste cooking oil must be treated to remove impurities before it can be converted into biodiesel. Average fatty acid composition in waste frying oil. The optimum conditions for biodiesel production methanol oils.
Cooking oil is used in substantial quantity for food frying either in home, restaurants or in food industry. Conversion of nolow value waste frying oils into biodiesel. The properties of the feedstock were determined using standard astm methods. Conversion of waste cooking oils into environmentally. Biodiesel is a fuel equal to the petrodiesel, the definition of biodiesel is as follows. Production of biodiesel from chicken frying oil emaad t. Jan 15, 2014 biodiesel was produced from waste frying oil using calcium oxide derived from the calcination of egg shell as a heterogeneous base catalyst. The production of biodiesel as renewable, easily biodegradable, and nontoxic alternative to fossil fuels is expensive when it is derived from virgin vegetable oils. Biodiesel consists of a mixture of monoalkyl esters and long chains of fatty acids derived from different types of oils and fats, obtained mostly via transesterification. Cost of biodiesel produced from virgin vegetable oil through transesterification is higher than that of fossil fuel, because of high raw material cost. Biodiesel from waste cooking oil linkedin slideshare. Materials and methods waste frying oil wfo was collected from local restaurant. With the increase in crude oil prices the need for development of economically attractive alternate fuels has increased.
Optimization of biodiesel production from waste cooking oil. Pretreatment of waste frying oils for biodiesel production. The biodiesel produced from vegetable oil or animal fat is usually more expensive than petroleumbased diesel fuel by 10 to 50 %. Constructional lime was supplied from construction workshop in campus. Bacon grease and other solid greases are not acceptable for biodiesel production since they raise the cloud point and could cause cold weather problems. Thienmethangkoonstatistical optimization for biodiesel production from waste frying oil through twostep catalyzed process fuel process technol, 92 2011, pp. Process optimization for biodiesel production from waste. In this context, waste frying oils transesterification was studied to obtain the maximum value of biodiesel. Biodiesel production from spent frying oil of fish via alkalicatalyzed transesterification.
The free fatty acids of the waste frying oil were esterified with alcohol cata lyzed by h. Conversion of waste cooking oil to biodiesel catalyst is limited only for refined vegetable oil with less than 0. Feasibility study of biodiesel and waste vegetable oil at. On a national level, biodiesel incorporated in the energy mix will encourage new business opportunities, greater investment, employment, and provide. Biodiesel or fatty acids alkyl esters faae of long chain are an alternative fuel produced by a transesterification process. Pdf pretreatment of waste frying oils for biodiesel.
As this method becomes increasingly popular, accumulation of waste generated from cooking oil. This can be shown by the acid value of the oil after 1st, 2nd and 3rd frying respectively. Apr 19, 2017 in this study, biodiesel was produced using waste cooking oil that was discarded as a waste in the environment. Preparation of biodiesel from waste frying oil using a green. It is the catalyst for transesterification and works by cracking the vegetable oil molecules, splitting the triglyceride from the hydrocarbons and shortening the carbon chain isopropyl alcohol. Due to the depletion of world petroleum reserves and increasing environmental concerns, the interest. Dont use a gas burner for this or any other stage of the biodiesel creation process. Biodiesel is a biofuel derived from vegetable oils andor animal fats. Waste oils are becoming increasingly more important as feedstock for the production of fuels and glycerol as byproduct. The project involves setting up of a laboratory scale production unit. In this respect, response surface methodology rsm was applied to determine the relationships between methanol and wfo. Mumbai and delhi is planted with jatropha and the train itself is being run on 1520% biodiesel3. No modifications are required, and the result is a lessexpensive, renewable, cleanburning fuel.
The aim of this research is to prepare biodiesel from fresh cooking oil and waste cooking oil, characterization of the two produced samples and comparison with european committee for standardization en 14214. The use of waste cooking oil as biodiesel feedstock reduces the cost of biodiesel production 7, 8. Physicochemical properties of biodiesel manufactured from. The environmental issues associated with the use of fossilbased energy sources have informed the search for more sustainable energy alternatives. Additionally, the use of waste fried cooking oil wfco as a reactant for biodiesel plant helps in disposing this waste and reduction of feedstock production. Recent strategy of biodiesel production from waste cooking. Life cycle assessment of biodiesel production from waste. Ethyl alcohol with sodium hydroxide as a catalyst was. The test was carried out at 200 bars for all the blends i. Biodiesel production from waste cooking oils wco is an attractive concern to produce biodiesel, but sometimes high cost for preparation and conversion from waste oil into biodiesel. Biodiesel production from waste frying oil using waste animal. Pdf biodiesel production from rapeseed oil with waste. Production of biodiesel from used vegetable oil beatrice onyinye ojiego 1. Nov 25, 2019 biodiesel is a diesel fuel that is made by reacting vegetable oil cooking oil with other common chemicals.
Biodiesel production from rapeseed oil with waste frying. Alternate fuels should be economically attractive in order to compete with currently used fossil fuels. Biodiesel may be used in any diesel automotive engine in its pure form or blended with petroleumbased diesel. Onestep alkaline koh catalytic process was employed in the production of the. Chrysikou 2, stella bezergianni 2 and mohamed bouaziz 1.
Biodiesel, transesterification, sunflower oil, waste cooking oil email. The usage of the vegetable oil as a source of fuel is as old as the diesel engine. In this context, waste frying oils transesterification was. In the first step, the main purpose was to reduce the acid value of the waste frying oil.
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